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Air Emissions from Modern Wood Energy SystemsBiomass Emissions.pdf (pdf) All combustion processes—whether the fuel is oil, gas, wood, or coal— emit dozens of exhaust components, all having different characteristics. The question of stack (chimney) emissions is further complicated by the incorrect assumption that what we know about residential wood stoves holds true for modern wood systems currently used in institutional, commercial, and utility settings. These wood systems are significantly cleaner than wood stoves for the following reasons:
Particulates Increasingly, concern about very fine particulates (2.5 microns and smaller) is receiving more attention by health and environmental officials for the same reasons. Work investigating wood and pellet boiler emissions of very fine particulates is ongoing. BERC will actively engage in this discussion and recommend changes in combustion techniques and pollution- control options as appropriate based on the state of the scientific information. All but the very best wood burning systems, whether in buildings or power plants, have significantly higher PM emissions than do corresponding gas and oil systems. For this reason, it is necessary to use a stack with a height that will effectively disperse emissions into the air and reduce ground-level concentrations of PM (and other pollutants) to acceptable levels. It should be noted that a conventional wood stove has PM emissions 500 times greater than a wood-fired power plant with sophisticated emissions control equipment, for the same amount of wood fuel input. School woodsystem chimneys emit virtually no visible smoke (the white plume of vapor on cold days is condensed water). Stack height is determined based on worst-case weather conditions and what is necessary to ensure air quality at the ground meets health-based standards. Currently, there is much greater risk from PM in the exhaust of idling school buses than from wood-heating plant emissions. Other Emissions Sulfur Oxides (SOx) cause acid rain. Modern wood systems have 1/6 the SO2 emissions of fuel oil. Nitrogen Oxides (NOx) cause ozone, smog, and respiratory problems. Wood and fuel oil combustion have similar levels of NOx emissions. Carbon Monoxide (CO) is produced by all fuel combustion processes. The level produced by wood combustion depends very much on how well the system is tuned, but is significantly higher than with oil. CO emissions from wood burning are of relatively minor concern to air quality regulators, however, except in areas like cities that have high levels of CO in the air from traffic exhaust. Volatile Organic Compounds (VOCs) are a large family of air pollutants, some of which are produced by fuel combustion. Some are toxic, others are carcinogenic. VOCs elevate ozone and smog levels in the lower atmosphere, causing respiratory problems. Both wood and oil combustion produce VOCs—wood is higher in some compounds and oil is higher in others. VOC emissions can be minimized with good combustion practices. Natural gas is the cleanest burning of all fuels, having significantly lower SOx and NOx emissions than wood or oil. The molecular structure of natural gas is very simple, compared to the complex chemical composition of wood and oil molecules, resulting in predictable, clean combustion for gas. Climate Change One of the most important environmental benefits of using sustainably produced wood for energy in place of fossil fuels is its positive impact in moderating long-term global climate change. Fossil fuel combustion takes carbon that was locked away underground (as crude oil, gas, or coal) and transfers that carbon to the atmosphere as new CO2. When wood is burned, on the other hand, it recycles carbon that was already in the natural carbon cycle, which is recaptured through sustainable forest growth. Consequently, the net long-term effect of burning wood fuel is that no new CO2 is added to the atmosphere — as long as the forests from which the wood came are sustainably managed.
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Anyone interested in wood heating systems wants to know the answer, at some level, to the question: 
